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Scientists examine over 1,000 chemicals from fracking fluids: many linked to reproductive or development toxicity

The indispensable chemical mixture that allows the industry to fracture rock and release the gas trapped inside looks almost like a black box. More than 1,000 chemicals are used in the fracking fluid, but a paper published in the Journal of Exposure Science and Environmental Epidemiology found toxicity information was lacking for 76% of them. In other words, these could be harmless or dangerous. There's no way to know at this point. Concerning the rest -- about 240 substances -- the researchers found evidence that suggests reproductive toxicity for 103 (43%), developmental toxicity for 95 (40%), and both for 41 (17%).

Tibi PuiubyTibi Puiu
January 11, 2016 - Updated on November 16, 2020
in Environmental Issues, News, Pollution
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The indispensable chemical mixture that allows the industry to fracture rock and release the gas trapped inside is basically a black box. More than 1,000 chemicals are used in the fracking fluid, but a paper published in the Journal of Exposure Science and Environmental Epidemiology found toxicity information was lacking for 76% of them. In other words, these could be harmless or dangerous. there’s no way to know at this point. Concerning the rest — about 240 substances — the researchers found evidence that  suggests reproductive toxicity for 103 (43%), developmental toxicity for 95 (40%), and both for 41 (17%).

fracking fire
Image: YouTube

Substances mentioned in the study include arsenic, benzene, cadmium, lead, formaldehyde, chlorine, and mercury. Of the 240 analyzed substances, 67 were particularly worrisome since these had an existing federal health-based standard or guideline. Like all hazardous chemicals, it’s the dose that matters. In the right concentration, a usually toxic chemical can be harmless. The researchers from Yale University say data on whether levels of chemicals exceeded the guidelines were too limited to assess.

“This evaluation is a first step to prioritize the vast array of potential environmental contaminants from hydraulic fracturing for future exposure and health studies,” said Nicole Deziel, senior author and assistant professor of public health. “Quantification of the potential exposure to these chemicals, such as by monitoring drinking water in people’s homes, is vital for understanding the public health impact of hydraulic fracturing.”

“We focused on reproductive and developmental toxicity because these effects may be early indicators of environmental hazards. Gaps in our knowledge highlight the need to improve our understanding of the potential adverse effects associated with these compounds,” said Elise Elliott, a public health doctoral student and the paper’s first author.

fracking-oil
Image: FracFocus

Fracking chemicals: a black box. Most drillers are not mandated to disclose the chemical makeup of fracking fluid, being treated as trade secrets.

According to Preserve the Beartooth Front, these findings from Yale echo previous research that found associations between proximity to hydraulic fracturing sites and reproductive and developmental problems. These include:

  • A 2013 Colorado study showed that exposure to frac water “could raise the risk of reproductive, metabolic, neurological and other diseases, especially in children who are exposed to EDCs [endocrine-disrupting chemicals].”
  • A 2014 Pennsylvania study looked at birth records to assess the health of infants born withina 2.5-kilometer radius of fracking sites. They found that proximity to fracking increased the likelihood of low birth weight by more than half.
  • A 2014 Colorado study examined the connection between how close a mother is to natural gas drilling and birth outcomes in a study of 124,842 births in rural Colorado between 1996 and 2009. The study shows an association between density and proximity of natural gas wells within a 10-mile radius of maternal residence and an increase of as much as 30% in the prevalence of congenital heart defects.

Earlier this year, the  U.S. Environmental Protection Agency (EPA) released a report in which it analyzed more than 39,000 FracFocus disclosures in the last two years.  The report found that the median number of chemical additives per fracking job was 14. Hydrochloric acid, methanol, and hydrotreated light petroleum distillates were the most common additives, being reported in 65 percent of all disclosures. Even in low doses, these are known to cause skin irritation, chemical burns, headaches and blurred vision.

In the past ten years, America has lived through what experts herald as the “shale boom” – a massive development of hydraulic fracturing wells to the point that today the U.S. has become the #1 crude oil and natural gas producer in the world. Nine out of ten wells in the U.S. are now fracking wells.

fracking

Essentially, hydraulic fracking wells pump a mixture of chemicals, sand and water some 2 miles deep into the ground. The pressure breaks down rock and releases the hydrocarbons previously trapped for millions of years.

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While fracking gave the U.S. a huge leverage, both economical and tactical, critics have voiced a number of valid concerns. These include air pollution, huge amounts of wastewater, bedrock fracturing that leads to earthquakes, and — maybe most worrisome — the potential for groundwater and aquifer contamination with hazardous chemicals. There are many other concerns, as well.

Researchers at University of Texas at Arlington conducted tests on more than 100 water wells in Texas and found 30% of these contained ‘alarming’ amounts of arsenic, enough to be considered carcinogenic and seriously threatening human health. These contaminated wells were found in the vicinity of known fracking sites and prior to drilling these were found to be free of arsenic or at least far from the concentrations we’re seeing now.

Today, however, there is no evidence that might directly link fracking to contaminated water, even though many people can now light their tap water on fire after fracking wells were developed in their vicinity. When Stanford researchers traced back methane leaks from contaminated drinking water in Pennsylvania and Texas to shale gas wells, they did not find a link between the contamination and the technique used to drill for shale gas itself. Instead, the researchers concluded that well integrity is the main driver for the contamination.

With good and bad, we need more long-term research on the matter to establish whether or not fracking is worth it. Frack now, ask questions later is not a wise course of action.

Update: corrected sub-heading citing fracking chemical as undisclosed and protected by patent laws.

Tags: frackinghydraulic fracturingYale University

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Tibi Puiu

Tibi Puiu

Tibi is a science journalist and co-founder of ZME Science. He writes mainly about emerging tech, physics, climate, and space. In his spare time, Tibi likes to make weird music on his computer and groom felines. He has a B.Sc in mechanical engineering and an M.Sc in renewable energy systems.

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