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Scientists witness the tiniest water droplet forming out of oxygen and hydrogen atoms in real-time

In effect, these were the smallest bubbles ever seen — and they made sure to record it.

Tibi Puiu
October 8, 2024 @ 1:07 am

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water droplet
Credit: Pixabay.

In a quiet lab at Northwestern University, a team of scientists peered into a high-powered microscope, holding their breath. What they saw was something no human had ever witnessed: the moment hydrogen and oxygen atoms merged to form water.

In effect, these were the smallest bubbles ever seen, shimmering on the surface of palladium.

The research led by Dr. Vinayak Dravid offers not only a glimpse of water’s molecular beginnings but also a roadmap for creating water in some of the most extreme environments on Earth — and perhaps even beyond it.

Making water out of thin air

For decades, scientists have known that palladium can catalyze the reaction to make water. Yet, despite years of study, the actual process remained shrouded in mystery. No one had ever been able to see the moment hydrogen and oxygen combine at such a microscopic scale.

“It’s a known phenomenon, but it was never fully understood,” said Yukun Liu, a Ph.D. student working in Dravid’s lab and the study’s first author. “Because you really need to be able to combine the direct visualization of water generation and the structure analysis at the atomic scale in order to figure out what’s happening.”

Then, nine months ago, everything changed. Dravid’s team developed a new method, using a thin, honeycomb-shaped membrane that trapped gas molecules and allowed the team to observe them in real-time under a powerful electron microscope. As the atoms collided and the reaction began, the researchers found themselves witnessing the birth of the tiniest water bubbles imaginable.

At first, the team could hardly believe what they were seeing. “We think it might be the smallest bubble ever formed that has been viewed directly,” Liu said. “It’s not what we were expecting. Luckily, we were recording it, so we could prove to other people that we weren’t crazy.”

A Blueprint for Space and Beyond

Dravid’s team wasn’t just interested in watching water form — they wanted to make the process faster. And that’s exactly what they did. They discovered that introducing hydrogen to the palladium before adding oxygen sped up the reaction dramatically. The hydrogen atoms slipped into the palladium’s lattice, causing it to expand. Then, when the oxygen was added, the reaction took off, forming water at the surface.

Though the experiment was on a small scale, the potential applications are vast. In the future, larger sheets of palladium could be used to generate much larger amounts of water. Dravid envisions a scenario where astronauts, heading to Mars or deep space, carry hydrogen-filled palladium with them. Once they reach their destination, all they would need to do is add oxygen to generate water for drinking or growing crops.

“Think of Matt Damon’s character, Mark Watney, in the movie ‘The Martian,’” said Dravid. “He burned rocket fuel to extract hydrogen and then added oxygen from his oxygenator. Our process is analogous, except we bypass the need for fire and other extreme conditions. We simply mixed palladium and gases together.”

The technology could also be used here on Earth, where many regions face water scarcity. According to the U.N., 1.1 billion people lack access to water, and 2.7 billion experience water scarcity at least one month a year. In deserts or other arid areas, this method could provide a way to generate clean water, simply by mixing gases. And while palladium might seem like an expensive solution, the team points out that it’s reusable — like any catalyst, palladium itself isn’t consumed and may be reused time and time again.

A Future Full of Possibilities

For now, the team is focused on refining the process and exploring how it might scale up for practical use. But their discovery opens the door to new ways of thinking about water — how it’s made, where it’s sourced, and how we might sustain life in the most inhospitable places.

It’s easy to forget how fundamental water is. We need it for everything — from drinking to growing food. But if we can generate it, out of thin air, in extreme environments? That could change everything.

As the tiniest water bubbles continue to shimmer in their lab, the team at Northwestern is already imagining the next steps.

The findings appeared in the Proceedings of the National Academy of Sciences.

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