homehome Home chatchat Notifications


Awesome chemistry experiment: the Briggs-Rauscher iodine oscillator

I recently stumbled upon this absolutely dazzling chemistry experiment, and I just had to share it. What you will see is a pretty rare reaction in chemistry – an oscillation reaction. Three clear solutions are combined, and the color gradually changes to amber. Suddenly, the whole thing goes dark blue! Then it stays blue, reverts […]

Mihai Andrei
February 28, 2012 @ 7:40 am

share Share

I recently stumbled upon this absolutely dazzling chemistry experiment, and I just had to share it. What you will see is a pretty rare reaction in chemistry – an oscillation reaction. Three clear solutions are combined, and the color gradually changes to amber. Suddenly, the whole thing goes dark blue! Then it stays blue, reverts to amber, and the whole cycle repeats again! Don’t believe me? Just take a look.

The chemical mechanism of this reaction is really complex, but the essentials rely on two different processes:

  • A (“non-radical process”): The slow consumption of free iodine by the malonic acid substrate in the presence of iodate. This process involves the intermediate production of iodide ion
  • B (“radical process”): A fast auto-catalytic process involving manganese and free radical intermediates, which converts hydrogen peroxide and iodate to free iodine and oxygen. This process also can consume iodide up to a limiting rate.

(via Wikipedia)

But here’s the catch: process B occurs only at low quantities of iodine, so this creates a loop. At first, the iodine quantity is quite low so the B process occurs, generating lots of iodine which accumulates. Meanwhile, process A becomes stronger and stronger, creating iodide from the generated iodine. At a certain point, this process overwhelms B, and the production of free iodine is stopped, but the substance is still consumed by A. After a while, the concentration becomes low enough for process B to happen again, and then the cycle repeats again. The color change you see is a result of the two processes.

share Share

Scientists Solved a Key Mystery Regarding the Evolution of Life on Earth

A new study brings scientists closer to uncovering how life began on Earth.

What Do Ancient Egyptian Mummies Smell Like? "Woody", "Spicy" and Even "Sweet"

Scientists used an 'electronic nose' (and good old biological sniffers) to reveal the scents of ancient mummies.

Why Beer Foam Lasts Longer in Belgian Ales Than in Anything Else

Why some beers keep their head longer than others—and what it means beyond brewing

Scientists Made 'Jelly Ice' That Never Melts. It's Edible, Compostable and Reusable

This squishy ice made from gelatin keeps things cold without the mess of melting.

World's Oldest Water is 1.6 billion Years Old -- and This Scientist Tasted It

Apparently, it tastes 'very salty and bitter'.

Frozen Wonder: Ceres May Have Cooked Up the Right Recipe for Life Billions of Years Ago

If this dwarf planet supported life, it means there were many Earths in our solar system.

New Hydrogel Is So Sticky It Can Hold a Rubber Duck to a Rock Through Crashing Ocean Waves

The new material can stick through waves, salt, and even high pressure.

Scientists Created a 3D Printing Resin You Can Reuse Forever

The new resin can be reused indefinitely without losing strength or quality.

This Startup Claims It Can Turn Mercury Into Gold Using Fusion Energy and Scientists Are Intrigued

The age-old alchemist's dream may find new life in the heart of a fusion reactor.

How Pesticides Are Giving Millions of Farmers Sleepless Nights

Pesticides seem to affect us in even more ways than we thought.